Bromine trifluoride autoionizes to form BrF and BrF. The shapes of the cation and anion are respectively ______, and ______.
Solution
Solution
Count electron pairs on bromine (7 valence electrons):
- BrF: electrons; 2 used in Br–F bonds, leaving 2 lone pairs. Four pairs in all (sp), two of them lone: bent.
- BrF: electrons; 4 used in bonds, leaving 2 lone pairs. Six pairs (spd), the two lone pairs opposite each other: square planar.
Answer: bent, square planar.
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